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Q1. Which equilibrium in gaseous phase would be unaffected by an increase in pressure?
Solution
b)
b)
Q2.Equivalent amounts of H2 and I2 are heated in a closed vessel till equilibrium is obtained. If 80% of the hydrogen can be
converted to H,the Kc at this temperature is
converted to H,the Kc at this temperature is
Solution
(a)
(a)
Q3. For the reaction,
CuSO4∙5H2O(s)⇌CuSO4∙3H2O(s)+2H2O(v) which one is correct representation?
CuSO4∙5H2O(s)⇌CuSO4∙3H2O(s)+2H2O(v) which one is correct representation?
Solution
d) k>sub>p=(P(H2O))^2 and Kc=[H2O]2 ; the solid species are not used in writing Kc or Kp
d) k>sub>p=(P(H2O))^2 and Kc=[H2O]2 ; the solid species are not used in writing Kc or Kp
Q4. One mole of nitrogen is mixed with 3 mole of hydrogen in a closed 3 litre vessel. 20% of nitrogen is converted into NH3.Then Kc for the 1/2 N2 +3/2 H2⇌NH3 is:
Solution
a)
a)
Q5.How many mole of HCl are required to prepare one litre of buffer solution (containing NaCN+HCl) of pH 8.5 using 0.01 g formula weight of NaCN (KHCN=4.1×10-10)?
Solution
a)
a)
Q6.Salting out action of soap is based on:
Solution
c) To precipitate soap from its saturated solution on addition of salt is called salting out action of soap. RCOONa⇌RCOO-+Na+ Ksp=[RCOO-][Na+] In presence of NaCl,[Na+] increases and thus, the product of [Na+][RCOO-] exceeds in Ksp to show precipitation of soap.
c) To precipitate soap from its saturated solution on addition of salt is called salting out action of soap. RCOONa⇌RCOO-+Na+ Ksp=[RCOO-][Na+] In presence of NaCl,[Na+] increases and thus, the product of [Na+][RCOO-] exceeds in Ksp to show precipitation of soap.
Q7.The oxoacid of SO2 is:
Solution
(a) S has +4 ox.no. in H2SO3 and SO2 both
(a) S has +4 ox.no. in H2SO3 and SO2 both
Q8.A white salt is readily soluble in water and gives a colourless solution with a pH of about 9. The salt would be:
Solution
b) Hydrolysis of CH3COO- give alkaline solution.
b) Hydrolysis of CH3COO- give alkaline solution.
Q9.The expression for the solubility product of Al2(SO4 )3 is
Solution
b) Al2(SO_4)3⇌2Al3++3SO42- Ksp=[Al3+]2 [SO42-]3
b) Al2(SO_4)3⇌2Al3++3SO42- Ksp=[Al3+]2 [SO42-]3
Q10. The suitable indicator for the titration of strong acid and weak base is
Solution
a) Such solutions are acidic and methyl orange act on acidic pH
a) Such solutions are acidic and methyl orange act on acidic pH